1887

Abstract

Summary

Firstly capillary trapping is examined in a range of five different rock types, including both carbonates and sandstones. Rocks are imaged both after drainage and imbibition, and in all cases between 65–70% of the CO2 in place after drainage was trapped. Trapped cluster size distributions are compared to rock connectivity as determined using pore network modelling. Better connected pore-spaces tend to have more large clusters relative to small clusters, and visa-versa. This is important as small clusters are more difficult to remobilise by viscous and gravitational forces. They also present a relatively larger surface area for reaction and mineralization.

Secondarily wettability is analysed by measuring contact angle manually. In order to do this the contact line was found in 3D and the data set resampled onto planes perpendicular to the contact line at a particular point. Contact angles ranging from 35–55o were found, indicating that the super-critical CO2-brine-carbonate system is weakly water wet. The range in contact angles is interpreted as the result of contact angle hysteresis associated with surface heterogeneity.

Finally the first images of CO2 drainage at reservoir conditions are also presented, imaged at Diamond Light Source, represented an unprecented depth of information about pore-scale flow processes.

Loading

Article metrics loading...

/content/papers/10.3997/2214-4609.20140848
2014-06-16
2024-04-18
Loading full text...

Full text loading...

References

  1. Bachu, S.
    , CO2 storage in geological media: Role, means, status and barriers to deployment. Progress in Energy and Combustion Science, 2008. 34(2): p. 254–273.
    [Google Scholar]
  2. Andrew, M.G., B.Bijeljic, and M.J.Blunt
    , Pore-scale imaging of trapped supercritical carbon dioxide in sandstones and carbonates. International Journal of Greenhouse Gas Control, 2014. In Press.
    [Google Scholar]
  3. Akbarabadi, M. and M.Piri
    , Relative permeability hysteresis and capillary trapping characteristics of supercritical CO2/brine systems: An experimental study at reservoir conditions. Advances in Water Resources, 2013. 52: p. 190–206.
    [Google Scholar]
  4. El-Maghraby, R.M. and M.J.Blunt
    , Residual CO2 Trapping in Indiana Limestone. Environmental Science and Technology, 2013. 47(1): p. 227–233.
    [Google Scholar]
  5. El-Maghraby, R.
    , Measurements of CO2 trapping in Carbonate and Sandstone Rocks, in Earth Science and Engineering2013, Imperial College, London.
    [Google Scholar]
  6. Pentland, C.H., et al.
    , Measurements of the capillary trapping of super-critical carbon dioxide in Berea sandstone. Geophysical Research Letters, 2011. 38: p. 4.
    [Google Scholar]
  7. Ennis-King, J. and L.Paterson
    , Engineering aspects of geological sequestration of carbon dioxide. SPE 77809, Proceedings of the Asia Pacific Oil and Gas Conference and Exhibition, 2002.
    [Google Scholar]
  8. Lin, H., et al.
    , Experimental evaluation of interactions in supercritical CO2/water/rock minerals system under geologic CO2 sequestration conditions. Journal of Materials Science, 2007. 43: p. 2307–2315.
    [Google Scholar]
  9. Lorenz, C.D. and R.M.Ziff
    , Precise determination of the bond percolation thresholds and finite-size scaling corrections for the sc, fcc and bcc lattices. Physical Review E, 1998. 57(1): p. 230–236.
    [Google Scholar]
  10. Amott, E.
    , Observations Relating to the Wettability of Porous Rock. SPE-1167-G. Petroleum Transactions, AIME, 1959. 216(1959): p. 156–162.
    [Google Scholar]
http://instance.metastore.ingenta.com/content/papers/10.3997/2214-4609.20140848
Loading
/content/papers/10.3997/2214-4609.20140848
Loading

Data & Media loading...

This is a required field
Please enter a valid email address
Approval was a Success
Invalid data
An Error Occurred
Approval was partially successful, following selected items could not be processed due to error