1887

Abstract

Summary

Implementation of the CO2-solubility model of into a simulation tool for the Bruchsal power plant yields results that indicate single-phase flow at 22 bar, at the production temperature of 124 °C, 130 g/L total dissolved solids and at a CO2-content of 0.3 wt.%. This, however, contradicts the observation in Bruchsal. The simulation was adjusted to 22 bar and 124 °C, yielding a CO2-content of 0.85 wt.%. The simulation is validated against gas breakout pressure measurements, which indicate that single-phase flow was not reached until 31.7 bar (operating conditions 22 bar). Using this pressure as a minimum value, the minimum CO2-content at single-phase conditions is estimated at 0.86 wt.%, which is in accordance with the results from the modified simulation tool. The general applicability of the new simulation tool has to be validated at other sites, before it can be implemented into a holistic power plant model. The successful validation at Bruchsal indicates that the new simulation tool and its implementation into holistic models is a promising tool for predicting NGC behaviour early in the development of geothermal power plants already in the exploration stage.

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/content/papers/10.3997/2214-4609.202021019
2020-11-16
2024-04-25
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References

  1. Denbigh, K.
    (1981): The Principles of Chemical Equilibrium. With Application in Chemistry and Chemical Engineering. Cambridge University Press.
    [Google Scholar]
  2. Duan, Z.; Møller, N.; Weare, J. H.
    (1992a): An equation of state for the CH4-CO2-H2O system: I. Pure systems from 0 to 1000°C and 0 to 8000 bar.Geochimica et Cosmochimica Acta56 (7), p. 2605–2617.
    [Google Scholar]
  3. (1992b): An equation of state for the CH4-CO2-H2O system: II. Mixtures from 50 to 1000°C and 0 to 1000 bar.Geochimica et Cosmochimica Acta56 (7), p. 2619–2631. DOI: 10.1016/0016‑7037(92)90348‑M.
    https://doi.org/10.1016/0016-7037(92)90348-M [Google Scholar]
  4. Duan, Z.; Sun, R.
    (2003): An improved model calculating CO2 solubility in pure water and aqueous NaCl solutions from 273 to 533 K and from 0 to 2000 bar.Chemical Geology193 (3–4), p. 257–271.
    [Google Scholar]
  5. Duan, Z.; Sun, R.; Zhu, C.; Chou, I-M.
    (2006): An improved model for the calculation of CO2 solubility in aqueous solutions containing Na+, K+, Ca2+, Mg2+, Cl−, and SO42−.Marine Chemistry98 (2–4), p. 131–139.
    [Google Scholar]
  6. Kölbel, L.; Kölbel, T.; Sauter, M.; Schäfer, T.; Siefert, D.; Wiegand, B.
    (2020). Identification of fracture zones in geothermal reservoirs in sedimentary basins: A radionuclide-based approach.Geothermics85.
    [Google Scholar]
  7. Linstrom, P.
    , Ed. (1997): NIST Chemistry WebBook, NIST Standard Reference Database69.
    [Google Scholar]
  8. Sanjuan, B.; Millot, R.; Innocent, C.; Dezayes, C.; Scheiber, J.; Brach, M.
    (2016): Major geochemical characteristics of geothermal brines from the Upper Rhine Graben granitic basement with constraints on temperature and circulation.Chemical Geology428, p. 27–47.
    [Google Scholar]
  9. Upton, P. S.; Santoyo, E.
    (2003): A comprehensive evaluation of empirical correlations for computing the solubility of CO2 in water. In: Stanford Earth (Hg.): Workshop on Geothermal Reservoir Engineering. Twenty-Eighth Workshop on Geothermal Reservoir Engineering.Stanford, California, January 27–29. Department of Energy Resources Engineering (Stanford University).
    [Google Scholar]
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