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Characterizing the pore structure of a reservoir using low field nuclear magnetic resonance (NMR) has been used extensively during the last decades by geologists and petrophysicists, providing important information for a more accurate evaluation of well producibility (e.g. porosity, permeability, pore-size distributions, saturation) ( Kenyon, 1997 ; Coates, 1999 ). Usually, the NMR transverse relaxation time (T2) decay is interpreted in terms of pore-sizes by the constant known of surface relaxivity (ρs), ( Kenyon, 1997 ; Keating and Knight, 2012 ). In clean and porous sandstones, the pore radius estimations using NMR can be successfully calculated (e.g. Fleury et al., 2007 ; Jácomo et al.; 2019 ), however in heterogeneous rocks with different compositions and magnetic susceptibilities, this relation produces a wide range of relaxivity ( Keating and Knight, 2012 ; Jácomo et al., 2020).
The Barra Velha Formation is the main pre-salt carbonate reservoir in Santos Basin (Southeast Brazil) and is highly studied. However, only some NMR studies investigated these carbonates, and none investigated the relaxivity ( Herlinger et al., 2018 ; Belila et al., 2020 ; Valle et al., 2021 ; Castro and Lupinacci, 2022 ). The objective of this work is to understand which factors can be a source for the range of relaxivity results. To accomplish this, we use petrographic, core routine analysis, NMR special petrophysics measurements, and X-ray microcomputed tomography (mCT) to calculate the relaxivity in Brazilian pre-salt carbonates.