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This study presents the first attempt to systematically detect and quantify unexploded ordnance (UXO) in the waters surrounding Jikdo, South Korea’s only live-fire maritime training range. A high-resolution marine geophysical survey was conducted using Side Scan Sonar (SSS) and a Multibeam Echo Sounder (MBES). To enhance detection accuracy and reduce subjectivity, a YOLO (You Only Look Once) deep learning algorithm was applied to acoustic imagery to identify UXO-like objects automatically. The detected targets were georeferenced using GIS and mapped onto bathymetric data to analyze spatial distribution. Results revealed that UXO-like anomalies were densely concentrated in the southwestern region of the survey area, particularly at depths between 40 and 50 meters—beyond the operational range of conventional diver-based methods. This study demonstrates the spatial limitations of traditional UXO detection and establishes the feasibility of integrating geophysical sensing with AI-based object detection for marine ordnance management. As the first application of this integrated method in Korean waters, the findings provide a foundational approach for data-driven, large-scale UXO risk assessment and clearance strategies in maritime military zones.