1887

Abstract

Summary

Storing CO2 in geological formations, especially deep saline aquifers, plays a vital role in carbon capture and storage (CCS), with significant potential to reduce greenhouse gas emissions. However, these aquifers with their high salinity impose the risk of salt precipitation on the process, which can cause pressurization and reduce injectivity. This study is focused on the topic of salt precipitation mitigation as developing such a strategy remains a challenge. This work proposes dissolved-water CO2 injection (dwCO2 injection) as an innovative method to prevent salt precipitation by dissolving water into CO2 prior to injection. The water presence in the CO2 stream prevents further water dissolution into CO2 (evaporation) and thus prevents salt precipitation. Two injection scenarios are examined using CMG-GEM commercial compositional simulator to evaluate the proposed method: a case with dry CO2 and another case with humid CO2. Results demonstrated that saturating CO2 with water nearly eliminated precipitation, while dissolving 2,000 ppmv water reduced salt precipitation by one-third.

Loading

Article metrics loading...

/content/papers/10.3997/2214-4609.202521054
2025-10-27
2026-01-19
Loading full text...

Full text loading...

References

  1. Barker, R., Hua, Y., Neville, A., 2017. Internal corrosion of carbon steel pipelines for dense-phase CO2 transport in carbon capture and storage (CCS)–a review. International Materials Reviews62, 1–31.
    [Google Scholar]
  2. Boot-Handford, M.E., Abanades, J.C., Anthony, E.J., Blunt, M.J., Brandani, S., Mac Dowell, N., Fernández, J.R., Ferrari, M.-C., Gross, R., Hallett, J.P., 2014. Carbon capture and storage update. Energy & Environmental Science7, 130–189.
    [Google Scholar]
  3. Buscheck, T.A., White, J.A., Carroll, S.A., Bielicki, J.M., Aines, R.D., 2016. Managing geologic CO 2 storage with pre-injection brine production: a strategy evaluated with a model of CO 2 injection at Snøhvit. Energy & Environmental Science9, 1504–1512.
    [Google Scholar]
  4. Cen, H., Cao, J., Chen, Z., Guo, X., 2019. 2-Mercaptobenzothiazole as a corrosion inhibitor for carbon steel in supercritical CO2-H2O condition. Applied Surface Science476, 422–434.
    [Google Scholar]
  5. Darkwah-Owusu, V., Md Yusof, M.A., Sokama-Neuyam, Y.A., Turkson, J.N., Fjelde, I., 2024. Assessment of Advanced Remediation Techniques for Enhanced CO2 Injectivity: Laboratory Investigations and Implications for Improved CO2 Flow in Saline Aquifers. Energy & Fuels.
    [Google Scholar]
  6. De Visser, E., Hendriks, C., Barrio, M., Mølnvik, M.J., de Koeijer, G., Liljemark, S., Le Gallo, Y., 2008. Dynamis CO2 quality recommendations. International journal of greenhouse gas control2, 478–484.
    [Google Scholar]
  7. Ding, S., Li, Y., Zhang, M., Xu, C., Wang, S., Gao, Y., Yu, H., Du, Y., Ma, J., 2024. Holistic Review on CO2 Geological Storage Potential Evaluation. Energy & Fuels, 19946–19965.
    [Google Scholar]
  8. Gale, J., Davison, J., 2004. Transmission of CO2—safety and economic considerations. Energy29, 1319–1328.
    [Google Scholar]
  9. Grude, S., Landrø, M., Dvorkin, J., 2014. Pressure effects caused by CO2 injection in the Tubåen Fm., the Snøhvit field. International Journal of Greenhouse Gas Control27, 178–187.
    [Google Scholar]
  10. Gunter, W., Gentzis, T., Rottenfusser, B., Richardson, R., 1997. Deep coalbed methane in Alberta, Canada:a fuel resource with the potential of zero greenhouse gas emissions. Energy Conversion and Management38, S217–S222.
    [Google Scholar]
  11. Hajiabadi, S.H., Bedrikovetsky, P., Borazjani, S., Mahani, H., 2021. Well Injectivity during CO2 geosequestration: a review of hydro-physical, chemical, and geomechanical effects. Energy & Fuels35, 9240–9267.
    [Google Scholar]
  12. Hansen, O., Gilding, D., Nazarian, B., Osdal, B., Ringrose, P., Kristoffersen, J.-B., Eiken, O., Hansen, H., 2013. Snøhvit: The history of injecting and storing 1 Mt CO2 in the fluvial Tubåen Fm. Energy Procedia37, 3565–3573.
    [Google Scholar]
  13. Kai, Y., XIANG, Y., Xiaoling, C., 2019. Investigation on corro⁃ sion characteristics of pipeline in CO2 ocean storage system. Corrosion Science and Protection Technology31, 672–680.
    [Google Scholar]
  14. Kestin, J., 1981. Experimental determination of the viscosity and thermal conductivity of fluids. Physics and Chemistry of the Earth13, 295–319.
    [Google Scholar]
  15. Kim, K.-Y., Han, W.S., Oh, J., Kim, T., Kim, J.-C., 2012. Characteristics of salt-precipitation and the associated pressure build-up during CO 2 storage in saline aquifers. Transport in porous media92, 397–418.
    [Google Scholar]
  16. Luna-Ortiz, E., Yao, C., Barnes, J., Winter, M., Healey, M., 2022. Development of A CO2 Specification for Industrial CCS Transport Networks: Methodology, Limitations and Opportunities, Offshore Technology Conference. OTC, p. D021S025R004
    [Google Scholar]
  17. Mim, R.T., Negash, B.M., Jufar, S.R., Ali, F., 2023. Minireview on CO2 Storage in Deep Saline Aquifers: Methods, Opportunities, Challenges, and Perspectives. Energy & Fuels37, 18467–18484.
    [Google Scholar]
  18. Oosterkamp, A., Ramsen, J., 2008. State-of-the-art overview of CO2 pipeline transport with relevance to offshore pipelines. Polytec Report number: POL-O-2007-138-A.
    [Google Scholar]
  19. Papi, A., Jahanbakhsh, A., Maroto-Valer, M.M., 2025. Preventing salt precipitation in CO2 storage processes in saline aquifers: Dissolved-water CO2 injection method. Energy & Fuels39, 3926–3941.
    [Google Scholar]
  20. Peysson, Y., André, L., Azaroual, M., 2014. Well injectivity during CO2 storage operations in deep saline aquifers—Part 1: Experimental investigation of drying effects, salt precipitation and capillary forces. International Journal of Greenhouse Gas Control22, 291–300.
    [Google Scholar]
  21. Qin, Z., He, Y., Wang, L., Liu, X., Ding, Y., Chen, Z., Li, B., Wang, Z., 2024. Analytical Model for Assessing the Impact of High-Rate CO2 Injection on Dry-out and Salt Precipitation in the Near-Wellbore Region of Saline Aquifers. Energy & Fuels38, 8875–8894.
    [Google Scholar]
  22. Robinson, D.B., Peng, D.-Y., Chung, S.Y., 1985. The development of the Peng-Robinson equation and its application to phase equilibrium in a system containing methanol. Fluid Phase Equilibria24, 25–41.
    [Google Scholar]
  23. Rowe Jr, A.M., Chou, J.C., 1970. Pressure-volume-temperature-concentration relation of aqueous sodium chloride solutions. Journal of Chemical and Engineering Data15, 61–66.
    [Google Scholar]
  24. Rubin, E., De Coninck, H., 2005. IPCC special report on carbon dioxide capture and storage. UK: Cambridge University Press. TNO (2004): Cost Curves for CO2 Storage, Part 2, 14.
    [Google Scholar]
  25. Sim, S., Cole, I.S., Choi, Y.-S., Birbilis, N., 2014. A review of the protection strategies against internal corrosion for the safe transport of supercritical CO2 via steel pipelines for CCS purposes. International Journal of Greenhouse Gas Control29, 185–199.
    [Google Scholar]
  26. Yang, S.O., Hamilton, S., Nixon, R., De Silva, R., 2015. Prevention of hydrate formation in wells injecting CO2 into the saline aquifer. SPE Production & Operations30, 52–58.
    [Google Scholar]
  27. Yazdanpanah, M., Galliot, L., Perrin, S., Moulie, G., Raurich, S., 2024. Review of CO2 Specifications in Novel Industrial CCS Transportation and Storage Hubs, Abu Dhabi International Petroleum Exhibition and Conference. SPE, p. D021S050R004.
    [Google Scholar]
  28. Zhang, G., Lu, P., Wei, X., Zhu, C., 2016. Impacts of mineral reaction kinetics and regional groundwater flow on long-term CO2 fate at Sleipner. Energy & Fuels30, 4159–4180.
    [Google Scholar]
/content/papers/10.3997/2214-4609.202521054
Loading
/content/papers/10.3997/2214-4609.202521054
Loading

Data & Media loading...

This is a required field
Please enter a valid email address
Approval was a Success
Invalid data
An Error Occurred
Approval was partially successful, following selected items could not be processed due to error